Electronic structure studies of multiferroic BiMn2O5 using X-ray absorption spectroscopy

Dinesh Kumar Shukla

Department of Physics, Aligarh Muslim University, Aligarh, India

Multiferroic BiMn2O5 in single phase polycrystalline has been synthesized using conventional solid state reaction method. Magnetic and dielectric properties investigated over the temperature range 4.2 K - 200 K, shows that the antiferromagnetic and ferroelectric transition temperatures (i.e. TN and TC) are in good agreement with the reported results. We present the X-ray absorption spectra (XAS) at the oxygen K edge and Mn L3,2 edge. The XAS pattern reveals that Mn in BiMn2O5 is having mixed valence state i.e. 4+ and 3+, where probability of Mn in 4+ state is more, which explicitly affects the ratio of Mn4+ to Mn3+, responsible for the magnetic ordering in the system at low temperatures.

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