One of the key achievements of equilibrium polymer physics is the prediction of scaling laws governing the viscoelastic properties of entangled polymer systems, validated in both natural polymers, such as DNA, and synthetic polymers, including polyethylene, which form materials like plastics. Recently, focus has shifted to active polymer systems composed of motile units driven far from equilibrium, such as California blackworms, self-propelled biopolymers, and soft robotic grippers. Despite their growing importance, their viscoelastic properties and universal scaling laws are not yet understood.
Christina Kurzthaler of the Max Planck Institute for the Physics of Complex Systems and her collaborators at the Technische Universität Darmstadt and the Heinrich Heine-Universität Düsseldorf have now investigated the viscoelastic properties of highly-entangled, flexible self-propelled polymers using Brownian dynamics simulations and scaling arguments. Their results demonstrate that activity enhances the elasticity by orders of magnitude due to the emergence of grip forces at entanglement points. Furthermore, activity fluidises the suspension, which is manifested by a lower viscosity than in the passive counterpart. These insights may open new avenues for designing activity-responsive polymeric materials.
Davide Breoni, Christina Kurzthaler, Benno Liebchen, Harmut Löwen, and Suvendu Mandal, Nat. Commun.
16, 5305 (2025)
See also the
press release by the Heinrich-Heine Universität Düsseldorf (in German).