Quantum aggregates are assemblies of monomers (molecules, atoms, quantum dots...), where the monomers largely keep their individuality. Interactions between the monomers can lead to collective phenomena, like superradiance or efficient excitation transfer. We study different kinds of aggregates (e.g. light harvesting systems, arrays of Rydberg atoms, self-assembled organic dyes...). Using various methods we study optical and excitation transport in these systems. Of particular interest is the coupling of the excitation to nuclear degrees of freedom.
NEWS
In the following an overview of recent results is given. A complete list of our publications can be found here.
Near field spectroscopy of molecular aggregates on dielectric surfaces

Parameter optimization using Gaussian processes

Dye Aggregates in Luminescent Solar Concentrators

We propose the design of a luminescent solar concentrator (LSC) in which dye aggregates with cylindrical geometry are embedded in the LSC plate with the long cylinder axis orthogonal to the faces of the plate. The most suitable aggregates are those exhibiting a blue-shifted (with respect to monomer absorption) H band and a narrow red-shifted J band. Such aggregates have high primary absorption into the H band which is polarized in the plane of the LSC and emission from the J band which is polarized perpendicular to the plane. Hence the emitted light is directed predominantly to the edges of the LSC and loss into the escape zone is much reduced. [Publication].
Dynamics of a single electron motor


Suppression of Quantum Oscillations in Electronic Excitation Transfer in the Fenna-Matthews-Olson Trimer


Energy transfer in the photosynthetic Fenna-Matthews-Olson (FMO) complex of green sulfur bacteria is studied numerically taking all three subunits (monomers) of the FMO trimer and the recently found eighth bacteriochlorophyll (BChl) molecule into account. The coupling to the non-Markovian environment is treated with a master equation derived from non-Markovian quantum state diffusion. When the excited-state dynamics is initialized at site eight, which is believed to play an important role in receiving excitation from the main light harvesting antenna, we see a slow exponential-like decay of the excitation. This is in contrast with the oscillations and a relatively fast transfer that usually occurs when initialization at sites 1 or 6 is considered. We show that different sets of electronic transition energies can lead to large differences in the transfer dynamics and may cause additional suppression or enhancement of oscillations [URL].
Equivalence of quantum and classical coherence in electronic energy transfer
To investigate the effect of quantum coherence on electronic energy transfer, which is the subject of current interest in photosynthesis, we solve the problem of transport for the simplest model of an aggregate of monomers interacting through dipole-dipole forces using both quantum and classical dynamics. We conclude that for realistic coupling strengths quantum and classical coherent transport are identical. This is demonstrated by numerical calculations for a linear chain and for the photosynthetic Fenna-Matthews-Olson complex. [URL]
Phase-directed energy transfer
The direction of excitonic energy transfer along a chain of monomers can be controlled by the phase of the initial state. In the picture initially the excitation is delocalised on two monomers with a phase difference of π/2 which leads to propagation mainly to the right. In addition the interaction between the monomers is designed such that the excitation does not disperse, but is focused at the end of the chain. The coupling strengths between nearest neighbors are shown in the upper panel. [URL]

Playing quantum-billiard with exotic atoms
Highly excited atoms (Rydberg atoms) have almost macroscopic dimension. We have seen that their extraordinary properties allow the construction of a microscopic version of Newton's cradle. Where the metal balls of a classical cradle only impart energy and momentum on one another, the Rydberg atoms in our micro version additionally hand over the delicate quantum property of "entanglement". Entanglement is a crucial ingredient of quantum computing and may even be involved in of the most important processes of life: photosynthesis. Thus, systems to control or study its migration may be of great relevance. [PDF] [URL]
